What are the chemical reactions upon which the photography industry relies


Kitten , Thursday, 12th of August 2010 08:03:15 PM

Just need a little help, l am working on a project for chemistry.
 
Kitten
 
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Main Squeeze , Friday, 13th of August 2010 12:29:19 PM

Hmmmm...been a while, but I do remember a few things. First in  
Main Squeeze
the process would be the development of the latent image (on exposed film)  
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into the solid silver image. Photo film emulsions are typically made from  
Joined: Friday, 11th of June 2010, 02:48:31
silver halides, the halides being typically bromide, chloride, etc.  
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When the silver halides (film emulsion) are struck by photons of light,  
the electrons in the valence band of the halides jump to the conduction  
(?) band, creating a latent (invisible) image awaiting development. The  
developer reacts with the exposed silver halides, converting them into  
solid silver. It actually reacts with all silver halides, but works much,  
much faster on the exposed molecules.  
 
The second step of film development is the stop bath: acetic acid. It  
halts development of the film by lowering the pH of the (alkaline)  
developer below it is working limit.  
 
The third step (b/w film & paper only) is the fixer, which dissolves the  
unexposed silver halides, leaving only the solid silver on a clear acetate  
base: b/w negative film.  
 
Lastly, the dissolved silver needs to be removed from the fixer for both  
environmental (silver is a heavy metal) & financial (silver is $$$)  
reasons. There are two primary methods: electrolytic & metallic  
replacement.  
 
Metallic replacement using a steel wool cartridge. Dissolved silver from  
the fixer reacts with the iron on the steel wool The more active iron ions  
are displaced, & the silver ions are retained on the wool creating what is  
called ''silver sludge which can be shipped to a refiner for extraction of  
the solid silver.  
 
Electrolytic recovery involves a low current between a cathode & anode.  
During this process the cathode is coated with near pure silver.  
 
I used to be able to diagram the chemical reactions for each step, but  
that was 20 years ago & my brain has long since filed such information  
into a deep, dark place from which it cannot be retrieved. Hopefully,  
something here will be helpful.  
 
 
 
 
 
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